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CAS 822-06-0

Hexamethylene Diisocyanate

Hexamethylene diisocyanate (HDI) is a highly reactive chemical used to make durable polyurethane paints and coatings, especially in auto body and industrial spray applications. It can harm the lungs and skin and can cause asthma even at low levels [1][2].

Where It Comes From

Two-part polyurethane coatings and hardeners; HDI monomer and HDI-based polyisocyanates in automotive refinish and industrial paints [2][3].

How You Are Exposed

Breathing vapors and fine spray droplets during mixing, spraying, and sanding/cleanup; skin and eye contact with liquid or overspray [1][2].

Why It Matters

Can cause sensitization and occupational asthma; once sensitized, even tiny exposures can trigger severe symptoms. Also irritates eyes, nose, throat, and skin [1][2].

Who Is at Risk

Auto refinishers, industrial painters, coating applicators, and anyone working in poorly ventilated areas; workers with asthma or allergies [2][3].

How to Lower Your Exposure

Use enclosed spray booths and local exhaust; choose non-isocyanate products when feasible; wear proper PPE—supplied-air respirator for spraying, chemical-resistant gloves/coveralls, eye protection; keep others out until coatings cure; report symptoms early and get medical evaluation [1][2][3].

References

  1. [1]CDC/NIOSH Pocket Guide to Chemical Hazards: Hexamethylene diisocyanate (HDI). https://www.cdc.gov/niosh/npg/
  2. [2]CDC/NIOSH Alert: Preventing Asthma and Death from Diisocyanate Exposure. DHHS (NIOSH) 96-111. https://www.cdc.gov/niosh/docs/96-111/
  3. [3]U.S. EPA. Diisocyanates Action Plan (TSCA), 2011. https://www.epa.gov/assessing-and-managing-chemicals-under-tsca/action-plans#diisocyanates

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