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CAS 64-18-6

Formic acid

Formic acid is a sharp‑smelling, corrosive liquid used in some cleaning/descaling products, agriculture, and industry. It also occurs naturally (ants, plants) and can form in polluted air; higher exposures usually happen at work or from misuse. [1][2]

Where It Comes From

Manufactured for leather/textile processing, rubber, and silage preservation; used in beekeeping to control mites; present naturally in ants/nettles; also formed in air from vehicle and solvent emissions. [1]

How You Are Exposed

Breathing vapors during cleaning or at work; skin/eye splashes; accidental swallowing; low indoor levels can come from consumer products. [1][2]

Why It Matters

Strong irritant/corrosive—can cause skin burns and serious eye damage; breathing high levels can trigger coughing, chest tightness, and lung injury; large doses can lead to metabolic acidosis. [1][2]

Who Is at Risk

Workers handling formic acid (leather/textiles, rubber, agriculture/silage, metal cleaning, labs, beekeeping); people with asthma or chronic lung disease; children if products are accessible. [1][2]

How to Lower Your Exposure

Use in well‑ventilated areas; wear chemical‑resistant gloves and eye protection; never mix with bleach or other cleaners; follow labels/SDS; store tightly closed and out of reach; at work, use local exhaust and PPE. [1][2]

References

  1. [1]WHO/IPCS. Concise International Chemical Assessment Document 15: Formic acid and sodium formate. 2001. https://inchem.org/documents/cicads/cicads/cicad15.htm
  2. [2]CDC/NIOSH. Pocket Guide to Chemical Hazards: Formic acid. https://www.cdc.gov/niosh/npg/npgd0293.html

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