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CAS 14866-68-3

CHLORATE

Organic Chemicals, except for PFASPesticides

Chlorate is a reactive chlorine compound that can form during drinking-water disinfection and is also used in some industrial and agricultural products. It matters because it can harm red blood cells and affect the thyroid. [1][2][3]

Where It Comes From

Forms when chlorine dioxide or hypochlorite (bleach) is used or stored; also from paper/pulp processing, herbicide use/production, and some pyrotechnics. [1][4]

How You Are Exposed

Mainly through drinking water treated with chlorine dioxide/bleach and foods washed or processed with chlorinated water; workers may inhale it or get skin contact. [1][3]

Why It Matters

High doses can cause methemoglobinemia, hemolysis, and kidney injury; repeated lower exposures have been linked to thyroid effects in animals and underpin EPA’s chronic reference dose. [2][3][1]

Who Is at Risk

Bottle-fed infants, pregnant people, those with thyroid disease, anemia or G6PD deficiency, kidney disease, and workers handling chlorate. [1][3]

How to Lower Your Exposure

Check your water report; if chlorate is elevated, consider reverse osmosis or anion exchange treatment; use fresh, properly stored bleach; avoid soaking foods in bleach and rinse produce; at work, follow controls and wear appropriate PPE. [1][4][3]

References

  1. [1]WHO. Chlorate and chlorite in drinking-water: Background document for development of WHO Guidelines for Drinking-water Quality. 2017.
  2. [2]U.S. EPA IRIS. Chlorate (CASRN 14866-68-3).
  3. [3]CDC/NIOSH Pocket Guide to Chemical Hazards: Sodium chlorate.
  4. [4]U.S. EPA. Alternative Disinfectants and Oxidants Guidance Manual. EPA 815-R-99-014, 1999.

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