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CAS 111984-09-9

3,3'-Dimethoxybenzidine monohydrochloride

This industrial chemical (a salt of o-dianisidine) is used to make certain azo dyes and pigments for textiles, inks, and plastics. It matters because o-dianisidine and its salts are linked to cancer, especially of the urinary tract (bladder) [1][2].

Where It Comes From

Made as a dye/pigment intermediate; can be present in manufacturing waste or released when some dyes break down [2][3].

How You Are Exposed

Mostly at work—breathing dust or vapors and skin contact with powders, wet cakes, or contaminated equipment; less often via air, dust, or water near facilities [3][4].

Why It Matters

Listed as “reasonably anticipated to be a human carcinogen” (NTP) and “possibly carcinogenic to humans” (IARC); causes tumors in animals and can irritate skin and eyes [1][2][4].

Who Is at Risk

Workers in dye/pigment manufacturing, printing/ink, textiles and leather, labs and maintenance; waste handlers; people living near production sites [3][4].

How to Lower Your Exposure

At work, use closed systems, local exhaust, protective gloves/eye protection, avoid dry sweeping, wash up and change clothes, and follow the SDS; in communities, follow local advisories and avoid potentially impacted water [4][3].

References

  1. [1]NTP. Report on Carcinogens: o-Dianisidine and o-Dianisidine Dihydrochloride. https://ntp.niehs.nih.gov/whatwestudy/assessments/roc
  2. [2]IARC Monographs. o-Dianisidine and its salts (Group 2B). https://monographs.iarc.who.int/list-of-classifications
  3. [3]EPA IRIS. o-Dianisidine (CASRN 119-90-4) Summary. https://iris.epa.gov/static/pdfs/0373_summary.pdf
  4. [4]CDC/NIOSH Pocket Guide to Chemical Hazards: o-Dianisidine. https://www.cdc.gov/niosh/npg/npgd0458.html

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