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CAS 75-68-3

1-Chloro-1,1-difluoroethane (HCFC-142b)

HCFC-142b is a colorless gas formerly used as a refrigerant, aerosol propellant, and foam-blowing agent. At high levels it can harm the heart and nervous system, and it depletes the ozone layer, so its use is being phased out [1][2][3].

Where It Comes From

Releases during manufacture and use of refrigerants and foams; leaks from older equipment and products; emissions from facilities. Some feedstock uses continue under controls [1].

How You Are Exposed

Breathing vapors at work or near industrial sites; leaks during equipment service; accidental skin/eye contact with the very cold liquid [2][3].

Why It Matters

Short-term exposure can cause dizziness, headache, and drowsiness; very high levels may trigger dangerous heart rhythm problems or unconsciousness; liquid can cause frostbite. It also depletes ozone and contributes to climate change [1][2][3].

Who Is at Risk

Workers in refrigerant, foam, or chemical manufacturing/servicing; people in poorly ventilated spaces; those with heart conditions may be more sensitive [2][3].

How to Lower Your Exposure

Replace or retrofit older HCFC-based equipment; promptly fix leaks and ventilate; recover refrigerant for recycling; follow local disposal rules; at work, use monitoring, training, and proper PPE [1][2].

References

  1. [1]U.S. EPA. Phaseout of Class II Ozone-Depleting Substances (HCFCs). https://www.epa.gov/ods-phaseout/phaseout-class-ii-ozone-depleting-substances
  2. [2]CDC/NIOSH. NIOSH Pocket Guide to Chemical Hazards: 1-Chloro-1,1-difluoroethane (HCFC-142b). https://www.cdc.gov/niosh/npg/
  3. [3]WHO/ILO/UNEP IPCS. International Chemical Safety Card: 1-Chloro-1,1-difluoroethane (HCFC-142b). https://www.ilo.org/dyn/icsc/showcard.display?p_lang=en&p_card_id= (search “HCFC-142b”)

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